Hi Melisande,
I popped your raw file into Canon DPP and see that this image was shot in AI focus (generally for moving subjects) and +2/3rds stop exposure. Using DPP I can see the lens focused using 7 focussing points and the two that probably achieved focus were over the model's right hand and her right knee. Personally I find focussing errors more user error when learning new kit and lens combo.
It's worth loading Canon DPP and running it if you continue to shoot raw and you'll be able to track any errors in focussing etc.
Switch to one shot focus for static models and I think you'll be better served. I'd also shoot a few frames on programme, jpegs too on standard and portrait settings in camera and see how they look before spending time on raws.
Hope this helps you. The 7D is a wonderful workhorse capable of producing some damn fine images. A friend of mine uses one on full auto everything including auto focuss points and gets fantastic images.