Uh, not... really. The PWs and YN-622c/Photix Odin/Pixel Kings are basically just relaying all five signals on the hotshoe. We know the hotshoe can do 2nd-curtain. The wireless protocol is not the hotshoe. When you invoke Canon's wireless protocol with any of these triggering systems, then you lose 2nd-curtain. With the YN-622c triggers, if wireless is enabled in the camera menu, you no longer have access to 2nd curtain.
Probably because you're using relatively normal shutter speeds and never shoot eTTL... Really, I'm not sure why 2CS isn't the default setting for on-camera and slave flashes. .... With eTTL, once your shutter speeds get low enough, the delay between the preflash and the actual flash with 2nd-curtain might be enough that your subject is caught full-blink (or in motion) on the actual flash burst. With 1st-curtain, you have the absolute shortest delay between preflash and main flash.