See if this helps. I just took three shots of a neutral gray card in dappled sunlight. (It's the wrong side of the card, but that is a trivial difference; I did it to have only gray in the image.) Here is the first shot, with the camera set to daylight (5200K):
It looks just like it should. Then I shot the same card with the camera set to shade and to tungsten. Setting it to shade (7000K) made it look yellow, and setting it to tungsten (3200K) made it look very blue. Here is the one from the tungsten setting:
Note that by setting the WB to a temperature that you associate with yellower colors, I turned the image blue. If I then put the LR eyedropper on it, LR resets the WB to 4950--almost the 5200 of the daylight setting--and the image now looks nearly identical to the first one.
So, what is happening? Why would setting the camera for tungsten light, which is more yellow, turn the neutral target blue? Because setting the camera for the tunsgsten setting is telling it that the lighting was tungsten
and that it should compensate for this yellowish light. Since the light wasn't actually tungsten, this is the wrong thing to do, and compensating for the yellow makes the image of the neutral target blue. When I used the LR eyedropper, I was instructing LR to consider that area neutral despite the WB setting it read from the file and to change the color temperature to the one that would have produced a neutral gray image.