Here's the newest edit... Do the eyes look better? This time I tried to get the color to match a little better, and did not sharpen them. I also left the contrast in the image alone, and tried to remove the blueberry stain under his lip (though I'm not entirely happy with how that turned out...). Better? Worse? Beyond hope? Thanks again to all of you for the suggestions!
Not sure what you are telling us here. I would still sharpen the whole image prior to posting as well as the eyes. The overall sharpening is to counter degradation in downsizing for the web and subsequent tinypix whatever they do.
Since the windows behind you were providing most of the light for the photo and the window right was over-exposing his left face so I think the suggestion to reduce the size of that window is valid from an exposure POV with the additional aspect that a smaller source is a sharper light source.
To improve what you have my solution was to make a selection with quite a lot of feather around the over-exposed side of the face and darken it, except this darkened the eye so that had to be undone. The warm tone on his right face isn't so noticeable when the left side is darkened. PSE#9 should be capable of all this.
Perhaps a quicker solution is to simply have one light source and use the on-board flash as your fill strongly reduced in power though this might not work with shots of the subject looking at the camera. My feelings at the moment is that modern cameras are very clever at working out the exposure provided they are given guidance as I'm suggesting.
Thanks for the explanation, John. I guess the biggest problem with this image is that I actually liked what I was seeing when talking the pictures, so I didn't change anything about the light. Had I been looking for more evenly distributed light, I would have played with closing the blinds a bit on his left and making sure the ones behind me were more open. As it was, I was mostly trying to apply advice from the Marissa thread on using short lighting to sculpt the face. I suppose I overdid it a bit here! I'll work towards finding a happy medium.
Thanks for the advice on pp, too. That makes sense.