I too have little experience with the GIMP.
You might find these related links of interest about the general subject of grayscale conversion:
http://cadik.posvete.cz/color_to_gray_evaluation/
http://cadik.posvete.cz/color_to_gra...Evaluation.pdf
There he talks about methods and audience ratings but with many, many illustrative images.
If you haven't tried de-composing a color into L*a*b* and using the L* lightness layer, that often works better for me than simple de-saturation.
Another trick I've used to get more contrast is to export a raw file from something like RawDigger with gamma = 1 instead of 2.2 which rewards you with lots of highlight contrast (of course). Or that command-line program 'dcraw' where you can convert with any gamma you like
As to your images, some might say that the trees could be a tad darker but with more local contrast compared to the light sky and foreground rocks - to get the classic "stark" look.
GIMP roolz OK . . .