You will find that over time that you develop an order, even inside these broad guidelines, that give you a workflow that you feel comfortable with because it lets you see the image in a way that shows you the way forward. Some people suggest that one follows the order that the software has laid out while others do things differently.
In Lightroom / Adobe Camera Raw, I rarely use anything other than the shadows and highlights sliders. I sometime use clarity and dehaze. I never use saturation and almost never use vibrance. I rarely use either the exposure or contrast sliders.
Most of my work is done in Photoshop.